高波利克

平成２７～２９年度　科学研究補助金（基盤研究Ｃ)
「ケイ素の特性を利用する光線力学的治療用ポルフィリン分子の創製」

平成２４～２６年度　科学研究補助金（基盤研究Ｃ）
「第三アミン及びスルフィドを基盤分子とする１電子移動型不斉有機触媒の創製」

平成２１～２３年度　科学研究補助金（基盤研究Ｃ）
「対面ポルフィリン二量体の超分子円二色性を利用する化合物の絶対配置決定法」

平成２０～２５年度　文部科学省ハイテクリサーチセンター整備事業「ゲノム情報に基づく合理的な創薬研究」


平成１７～１９年度　科学研究補助金（基盤研究Ｃ）
「多分子担持型フタロシアニン固相担体を用いる固－液ハイブリッド合成法の開発」

平成１６～１８年度　科学研究補助金（基盤研究Ｃ）
「対面型ポルフィリン２量体による不斉空間の構築


野地匡裕

平成２４～２６年度　科学研究補助金（基盤研究Ｃ）
「カルボカチオンに対する面選択的反応の開発」

平成１８～２０年度　科学研究補助金（若手研究B)
「カルボカチオンに対する面選択的反応とその制御」


林　賢 

平成２７～２９年度　科学研究補助金（若手研究B)
「光スイッチ機能を持つポルフィリン二量体を基盤分子とする酸素酸化触媒の開発」

An Immobilized Vanadium-binaphthylbishydroxamic Acid Complex as a Reusable Catalyst for the Asymmetric Epoxidation of Allylic Alcohols
Noji, M., Kondo, H., Yazaki, C., Yamaguchi, H., Ohkura, S., Takanami, T.,Tetrahedron Lett. 2019, 60, 1518–1521.

Chiroptical Protocol for the Absolute Configurational Assignment of Alkyl-Substituted Epoxides Using Bis(zinc porphyrin) as a CDSensitive Bidentate Host
Takeda, S., Hayashi, S., Noji, M., Takanami, T.,J. Org. Chem. 2019, 84, 645-652.

Preparation of meso-silylporphyrins via nickel-catalyzed coupling of meso-brominated Ni(II) porphyrins with silylzinc reagents
Hayashi S, Endo T, Takanami, T, Heterocycles, 2018, 97, 1082-1098.

Coumarins with an unprecedented tetracyclic skeleton and coumarin dimers from chemically engineered extracts of a marine-derived fungus
Kamauchi H, Noji M, Kinoshita K, Takanami T, Koyama K Tetrahedron, 2018, 74, 2846-2856.

Diastereoselective Synthesis of 2,4-Substituted Tetrahydroquinolines via Hf(OTf)₄
Catalyzed Substitution/Cyclization of 2-Aminobenzyl Alcohols with Styrenes
Noji, M.; Kadowaki, H.; Kubota, Y.; Yoshida, T.; Saito, N.; Yamaguchi, S.; Ohata, R.; Ishii, K.;
Takanami, T. Heterocycles, 2017, 95, 1041-1073.

Palladium-catalyzed Cross-coupling Reactions of Brominated Porphyrins with Functionalized
Organomagnesium Reagents: Direct Preparation of Functional-Group-Bearing Free Base Porphyrins
Sugita, N.; Tsuchiya, I.; Takanami, T. Heterocycles, 2016, 93, 483-511.

Regioselective β-Silylation of Porphyrins via Iridium-Catalyzed C–H Bond Activation
Sugita, N.; Hayashi, S.; Shibata, M.; Endo, T.; Noji, M.; Takatori, K.; Takanami, T. Org. Biomol. Chem. 2016, 14, 10189-10192.

Bis(zinc porphyrin) as a CD-Sensitive Bidentate Host Molecule: Direct Determination of Absolute Configuration of Mono-Alcohols
Hayashi, S.; Yotsukura, M.; Noji, M.; Takanami, T. Chem. Commun. 2015, 51, 11068-11071.

Asymmetric Epoxidation of Allylic Alcohols Catalyzed by Vanadium–Binaphthylbishydroxamic Acid Complex
Noji, M.; Kobayashi, T.; Uechi, Y.; Kikuchi, A.; Kondo, H.; Sugiyama, S.; Ishii, K. J. Org. Chem. 2015, 80, 3203–3210.

Functionalization of Porphyrins through C-C Bond Formation Reactions with Functional Group-Bearing Organometallic Reagents
Takanami, T. Heterocycles, 2013, 87, 1659-1689 (Review).

Palladium-catalyzed Kumada Coupling Reaction of Bromoporphyrins with Silylmethyl Grignard Reagents: Preparation of Silylmethylsubstituted Porphyrins as a Multipurpose Synthon for Fabrication of Porphyrin Systems
Sugita, N.; Hayashi, S.; Hino, F.; Takanami, T. J. Org. Chem. 2012, 77, 10488−10497 (Featured Article).

An Efficient One-Pot Protocol for Asymmetric Bifunctionalization of 5,15-Disubstituted Porphyrins: Direct Access to meso Activated Alkenyl-Substituted meso-Formylporphyrins
Takanami, T.; Hayashi, S.; Iso, K.; Matsumoto, J.; Hino, F. Tetrahedron Lett. 2011, 52, 5345.

An Efficient One-Pot Procedure for Asymmetric Bifunctionalization of 5,15-Disubstituted Porphyrins: A Simple Preparation of meso Acyl-, Alkoxycarbonyl-, and Carbamoyl-Substituted meso-Formylporphyrins
Takanami, T.; Wakita, A.; Matsumoto, J.; Sekine, S.; Suda, K. Chem. Commun. 2009, 101.

Metallophthalocyanine Complex, Cr(TBPC)OTf: An Efficient, Recyclable Lewis Acid Catalyst in the Regio- and Stereoselective Rearrangement of Epoxides to Aldehydes
Suda, K.; Nakajima, S.; Satoh, Y.; Takanami, T. Chem. Commun. 2009, 1255.

A Facile One-Pot Preparation of meso-Hydroxymethylporphyrins via a Sequential S_NAr Reaction with (2-Pyridyldimethylsilyl)methyllithium Followed by Hydrolysis and Aerobic Oxidation
Takanami, T.; Matsumoto, J.; Kumagai, Y.; Sawaizumi, A.; Suda, K. Tetrahedron Lett. 2009, 50, 68.

特異な反応場を持つルイス酸触媒としての金属ポルフィリンおよび
フタロシアニン錯体
高波利克、須田晃治 有機合成化学協会誌 2009, 67, 595.

希土類及びハフニウムトリフラートを用いたカルボカチオン生成と各種求核試薬の反応
野地匡裕、石井啓太郎 有機合成化学協会誌 2009, 67, 114–122.

Highly Regioselective Rearrangement of 2,3-Diaryloxiranes into 2,2-Diarylacetaldehydes Catalyzed by Yitterbium Porphyrin Complex, Yb(TPP)OTf
Takanami, T.; Nakajima, S.; Nakadai, S.; Hino, F.; Suda, K. Heterocycles 2009, 77, 365.

A Facil and Efficient Synthesis of Mono- and Bisfunctionalized meso-Substituted Porphyrins via Palladium-Catalyzed Negishi Cross-Coupling
Takanami, T.; Yotsukura, M.; Inoue, W.; Inoue, N.; Hino, F.; Suda, K. Heterocycles 2008, 76, 439.

One-Pot Synthesis of meso-Formylporphyrins by S_NAr Reaction of 5,15-Disubstituted Porphyrins with (2-Pyridyldimethylsilyl)methyllithium
Takanami, T.; Wakita, A.; Sawaizumi, A.; Iso, K.; Onodera, H.; Suda, K. Org. Lett. 2008, 10, 685.

9,10-Disubstituted Octafluoroanthracene Derivatives via Palladium-Catalyzed Cross-Coupling
Tannaci, J. F.; Noji, M.; McBee, J. L.; Tilley, T. D. J. Org. Chem. 2008, 73, 7895−7900.

A Novel Synthetic Route to 2-Arylalkanoic Acids by a Ruthenium-Catalyzed Chemoselective Oxidation of Furan Rings
Noji, M.; Sunahara, H.; Tsuchiya, K.; Mukai, T.; Komasaka, A.; Keitaro Ishii Synthesis 2008, 3835−3845.

9,10-Dichlorooctafluoroanthracene as a Building Block for n-Type Organic Semiconductors
Tannaci, J. F.; Noji, M.; McBee, J.; Tilley, T. D. J. Org. Chem. 2007, 72, 5567−5573.

Metal Triflate-Catalyzed Cationic Benzylation and Allylation of 1,3-Dicarbonyl Compounds
Noji, M.; Konno, Y.; Ishii, K. J. Org. Chem. 2007, 72, 5161−5167.

Highly Regioselective [3,3] Rearrangement of Aliphatic Allyl Vinyl Ethers Catalyzed by a Metalloporphyrin Complex, Cr(TPP)Cl
Takanami, T.; Hayashi, M.; Iso, K.; Hirose, N.; Suda, K. Tetrahedron 2006, 62, 9467

Palladium-Catalyzed Cyanation of Porphyrins Utilizing Cyanoethylzinc Bromide As an Efficient Cyanide Ion Sou
Takanami, T.; Hayashi, M.; Chijimatsu, H.; Inoue, W.; Suda, K. Org. Lett. 2005, 7, 3937

Metalloporphyrin Cr(TPP)Cl-Catalyzed Claisen Rearrangement of Simple Aliphatic Allyl Vinyl Ethers and Its Unique Stereoselectivity
Takanami, T.; Hayashi, M.; Suda, K. Tetrahedron Lett. 2005, 46, 2893.

Highly Regio- and Stereoselective Rearrangement of Epoxides to Aldehydes Catalyzed by High-Valent Metalloporphyrin Complex, Cr(TPP)OTf
Suda, K.; Kikkawa, T.; Nakajima, S.; Takanami, T. J. Am. Chem. Soc. 2004, 126, 9554.

Palladium-Catalyzed meso-Amination and Amidation of Porphyrins: Marked Acceleration with the Ni(II) Centralmetal Ion
Takanami, T.; Hayashi, M.; Hino, F.; Suda, K. Tetrahedron Lett.2003, 44, 7353.

Secondary Benzylation Using Benzyl Alcohols Catalyzed by Lanthanoid, Scandium, and Hafnium Triflate
Noji, M.; Ohno, T.; Fuji, K.; Futaba, N.; Tajima, H.; Ishii, K. J. Org. Chem. 2003, 68, 9340−9347.

High-Valent Metralloporphyrin, Fe(tpp)OTf, Catalyzed Rearrangement of α,β-Epoxy Ketones into 1,2-Diketones
Suda, K.; Baba, K.; Nakajima, S.; Takanami, T. Chem. Commun. 2002, 2570.

Reaction of cis-2,3-Bis(trimethylsilyl)cyclopropanone with β-Ketophosphorus Ylides: Unexpected Formation of Furans
Takanami, T.; Ogawa, A.; Suda, K. Tetrahedron Lett. 2000, 41, 3399.